Summary
Large quantities of rubies from the new
deposit at Mong Hsu have been widely available since 1992. Most
are heat-treated before they enter the jewelry trade. Mong Hsu
rubies are easily recognized by their distinctive microscopic
properties. They have a number of features that thus far have not been reported for
rubies from other localities. These include:
a) distinct color
zoning confined to specific growth structures, with one or two violet
"cores" surrounded by a red "rim"; b)
spectroscopic features in the red to yellow portion of the visible spectrum, with
absorption bands that are removed during heat treatment to change
the cores from violet to red; c) presence of whitish particles
in certain growth zones, formed as a result of heat treatment.
Color zoning in Mong Hsu rubies is closely
related to a complex chemical zoning confined to growth layers formed parallel to the basal pinacoid, to the positive
rhombohedron, and to two hexagonal dipyramids. There is a distinct growth sequence whereby
red and violet areas formed in various growth cycles, with a specific habit change between
different growth zones.
The formation conditions of rubies have been
reconstructed following the study of mineral associations and fluid inclusion analyses.
Mong Hsu rubies were formed at 2-2.5 kbars and at temperatures between 500oC and 550oC.
The fluids were found to be water-bearing and multi-volatile
CO2-rich. Fluorite inclusions in the rubies indicate that fluids
must have contained some HF. For further details see the role of
fluorine in the formation of color zoning.
The distinctive properties of Mong Hsu
rubies are useful in separating faceted samples from their counterparts in also in
establishing the locality of origin. The most prominent diagnostic properties of faceted, heat-treated Mong Hsu rubies require careful microscopic
examination, using immersion techniques in conjunction with fiber-optic illumination.
Key features include growth structures
confined to a distinct color zoning between cores and rims; different types of whitish particles and whitish streamers are
also of diagnostic value. Specialized laboratory techniques, such as XRF
analysis and IR spectroscopy, provide additional diagnostic information.
Problems for the trade arise, however, from
the large numbers of stones with fractures that appear to have been filled with a foreign
material, especially partially healed fractures with glassy
and/or crystalline fillers.